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姓名:韩一帆
职称:教授
所属单位:华东理工大学
电话:021-64251928
传真:021-64251928
电子邮件:yifanhan@ecust.edu.cn
网页:http://skloche.ecust.edu.cn/yfhan

教育背景:
1994/09-1997/07,华东理工大学 有机化工专业 博士研究生
1991/09-1994/07,华东师范大学 化学系 物理化学专业 硕士研究生

工作经历:
2009/09-至今,华东理工大学化工学院化学工程国家重点实验室,校特聘教授、化学工程专业博士生导师
2004/11-2009/09,新加坡科技研究局化学与工程科学研究院高级研究员
2004/11-2009/09,新加坡科技研究局化学与工程科学研究院高级研究员
1999/04-2003/02,德国ULM大学表面与催化系博士后
1997/09-1999/04,复旦大学化学系博士后

研究方向:
现场原位催化表征,化学工程,催化剂工程,能源与环境催化

学术要点:
1.动态现场原位催化表征
动态现场原位拉曼光谱:发展动态现场原位(Operando)拉曼光谱技术,在分子水平探索反应条件变化对催化剂结构的影响,实现在反应过程中催化剂的动态结构变化跟踪,发展工业催化剂研究理论。
动态现场原位红外光谱:发展原位红外光谱系统(DRIFTS),实现在反应条件下对催化材料结构及表面物种变化的实时跟踪,揭示反应条件下催化剂表面微观结构以及氧化态变化,研究催化反应机理。
2、能源与环境催化
煤化工催化剂方向:设计氧化及合成气转化反应催化剂应用于洁净能源生产、绿色化工和环境净化领域。研究由合成气直接生产高附加值化学品(C2-C4烯烃,低碳醇等)催化反应过程,内容包括:催化剂制备、催化剂结构表征、反应动力学、反应机理模型、DFT计算、催化剂宏量制备等。
水处理方向:研究水中微量污染物如微量剧毒有机物、重金属离子等的清除方法。主要通过发展固体Fenton催化系统,以过氧化氢为原料,催化分解产生氢氧自由基深度氧化污染物种,达到完全解除目的,且无二次污染。该法可大幅减低污水排放的COD,使工业污水达到国家排放标准。
3、工业催化剂构-效关系研究
催化反应动力学:通过谱学技术与原位池的统一设计,进行气-固、液-固、气-液-固不同类型反应的动力学研究,建立催化反应动力学模型,并结合动态原位光谱,深入研究反应机理。此外,通过DFT计算探索化学反应微观动力学,包括反应路径、速率控制步骤、反应表观活化能等。
纳米催化剂构-效关系研究:在催化剂的“理性设计、可控制备”研究思路指导下研究尺寸和形貌可控的纳米催化剂制备技术。探讨纳米催化剂宏量制备工艺,探索具有新颖结构纳米催化剂在低温催化氧化反应中的应用: 如一氧化碳氧化、甲烷和VOC低温燃烧、过氧化氢的合成等。 同时,通过反应动力学、DFT计算和各种动态现场原位表征技术,研究催化剂结构在反应过程中的变化,构建催化剂构-效关系,为催化剂理性设计提供理论指导。

荣誉和奖励:
2010年“上海市浦江人才”,2012年“上海市千人计划专家”。
主持或参与985平台、自然科学基金委、上海市科委等项目共20多项。在专业顶级期刊JACS、J.Catal、AIChE J等发表论文95 篇,SCI国际期刊论文73篇,一作或通讯54篇,影响因子大于4.0的SCI源刊物论文36篇,SCI他引1376次,H因子24,单篇最高SCI他引91次;申报国际专利1项、国家发明专利8项、获洲际会议大奖1项(第一获奖人)。近五年代表性论文JACS 3篇,AIChE J. 2篇,J. Catal. 4篇。应邀撰写综述2篇,国际学术邀请报告10次。2012年起,担任英国皇家化学会催化书籍编辑,主编(著)催化专业书籍3卷(英文)。2010年入选上海市浦江人才;2012年入选上海“千人计划”专家。相关工业催化剂研制新策略获得工业界高度关注,与世界500强化工公司紧密合作提高工业催化研发效率。

代表性论文:
[1]Junjie Su, Wei Mao, Xin-Chao Xu, Zhen Yang, Honglin Li, Jing Xu, Yi-Fan Han*,“Kinetic Study of Higher Alcohol Synthesis Directly from Syngas over CoCu/SiO2 Catalysts”, AIChE J., 2014, 60,1797.
[2]Junjie Su, Wei Mao, Zhen Yang, Jing Xu, Yifan Han *, “Kinetics of CoCu/SiO2 for Synthesis of Lower Carbon Mixed Alcohols Directly from Syngas”, CISEC J., 2014, 65,143-151.
[3]Like Ouyang, Guo-jin Da, Peng-fei Tian, Tian-yuan Chen, Guo-da Liang, Jing Xu and Yi-Fan Han*, “Insight into active sites of Pd-Au/TiO2 catalysts in hydrogen peroxide synthesis directly from H2 and O2”, J. Catal., 2014, 311, 129-136.
[4]Xinhai Yu, Wei Yu, Hongliang Li, Shan-Tung Tu, Yi-Fan Han, Preparation, characterization and application of K-PtCo/Al2O3 catalyst coatings for preferential CO oxidation, Appl. Catal. B: Environ., 2013, 140-141, 588-597.
[5]Like Ouyang, Guojin Da, Pengfei Tian, Tianyuan Chen, Jing Xu, Yifan Han*, “Kinetic Study of Synthesis of Hydrogen Peroxide Directly from H2 and O2 over Pd/HAp Catalyst”, CISEC J., 2014, 65,152-159.
[6]Xue-jing Yang, Xi-meng Xu, Jing Xu, Yi-Fan Han*, “Iron Oxychloride (FeOCl): An Efficient Fenton-Like Catalyst for Producing Hydroxyl Radicals in Degradation of Organic Contaminants”, J. Am. Chem. Soc., 2013, 43, 16058–16061.
[7]Guo-Jin Da, Like Ouyang, Jing Xu, Yi-Fan Han*, “Pyridine modified Pd/SiO2 catalyst for direct synthesis of H2O2”, CISEC J., 2013, 64, 561-567.
[8]Jing Xu, Ya-Qing Deng, Yan Luo, Wei Mao, Xue-Jing Yang, Yi-Fan Han*, “Operando Raman spectroscopy and kinetic study of low-temperature CO oxidation on an α-Mn2O3 nanocatalyst”, J. Catal., 2013, 300, 225-234.
[9]Jing Xu, Like Ouyang, Wei Mao,Xue-Jing Yang, Xin-Chao Xu, Jun-Jie Su, Hui Li, Yi-Fan Han*, “Operando and Kinetic Study of Low-temperature Lean-burn Methane Combustion over a Pd/α-Al2O3 Catalyst”, ACS Catal., 2012, 2, 261-269.
[10]Pengfei Tian, Like Ouyang, Xinchao Xu, Jing Xu, Yi-Fan Han*, “A DFT Study of the Direct Synthesis of H2O2 from H2 and O2 on Pd(111), Pd(100) and Pd(110) Surfaces”, Chin. J. Catal., 2013, 34, 1002-1012
[11]Like Ouyang, Guo-Jin Da, Jun Ni, Jing Xu and Yi-Fan Han*, Heterogeneous catalysis by gold-based bimetallic catalysts, Recent Patents on Catalysis, 2013, 2, 2-46.
[12]Xuejing Yang, Peng-Fei Tiana, Chengxi Zhang, Ya-qing Deng, Jing Xu, Jinglong Gong, Yi-Fan Han*, “Au/carbon as Fenton-like catalysts for the oxidative degradation of bisphenol A”, Appl. Catal. B: Environ., 2013, 134-135, 145- 152
[13]Yan Luo, Ya-Qing Deng, Wei Mao, Xue-Jing Yang, Kake Zhu, Jing Xu, and Yi-Fan Han*, “Probing the Surface Structure of α-Mn2O3 Nanocrystals during CO Oxidation by Operando Raman Spectroscopy”, J. Phy. Chem. C., 2012,116, 20975–20981
[14]Jing Xu, Xin-Chao Xu, Like Ouyang, Xue-jing Yang, Wei Mao, Junjie Su, Yi-Fan Han*,“Mechanistic study of preferential CO oxidation on a Pt/NaY Zeolite Catalyst”, J. Catal., 2012, 287, 114-123.
[15]Jing Xu, Like Ouyang, Yan Luo, Xi-Meng Xu, Zhen Yang, Chengxi Zhang and Jinlong Gong*, Yi-Fan Han*,“Mechanistic Insights into Methanol-to-Olefin Reaction on an α-Mn2O3 Nanocrystal Catalyst”, AIChE J. 2012, 58, 3474–3481.
[16]Jing Xu, Like Ouyang, Guo-Jin Da, Qian-Qian Song, Xue-Jing Yang, Yi-Fan Han*, “Pt Promotional Effects on Pd-Pt Alloy Catalysts for Hydrogen Peroxide Synthesis Directly from Hydrogen and Oxygen”, J. Catal., 2012, 285,74-82.
[17]Jing Xu, Tim White, Ping Li, Chongheng He, Yi-Fan Han*, “Hydroxyapatite Foam as a Catalyst for Formaldehyde Combustion at Room Temperature”, J. Am. Chem. Soc., 2010, 132, 13172–13173.
[18]Jing Xu, Tim White, Ping Li, Chongheng He, Jianguo Yu, Weikang Yuan, and Yi-Fan Han*, “Biphasic Pd-Au Alloy Catalyst for Low-Temperature CO Oxidation”, J. Am. Chem. Soc., 2010,132,10398-10406.
[19]Kanaparthi Ramesh, Chang Jie, Yi-Fan Han and Armando Borgna, “Synthesis, Characterization, and Catalytic Activity of Phosphorus Modified H-ZSM-5 Catalysts in Selective Ethanol Dehydration”, Ind. Eng. Chem. Res., 2010, 49, 4080-4090.
[20]Jing Xu, Ping Li, Xingfu Song, Chongheng He, Jianguo Yu and Yi-Fan Han*,“Operando Raman Spectroscopy for Determining the Active Phase in One- Dimensional Mn1?xCexO2±y Nanorod Catalysts during Methane Combustion”, J. Phys. Chem. Lett., 2010, 1, 1648–1654.
[21]Jing Xu, Ping Li, Xingfu Song, Zhiwen Qi, Jianguo Yu, Weikang Yuan and Yi-Fan Han*, “Kinetic Study of H2 Oxidation in the Preferential Oxidation of CO on a Nanosized Au/CeO2 Catalyst”, Ind. Eng. Chem. Res., 2010, 49, 4149-4155.
[22]Ping Li, Chongheng He, Sandro Campestrini, Benedetto Corain, Weikang Yuan and Yi-Fan Han*, “Synthesis of Hydrogen Peroxide from H2 and O2 in Water and Ethanol Catalyzed by Nanoclustered Pd0 on Silica: Strong Selectivity Enhancement Exerted by the Addition of Ionic Liquids”, Phys. Chem. Chem. Phys., 2010, 12, 2170-2176.
[23]Ang Thiam Peng; Law Jia Yan; Han Yi-Fan, “Preparation, Characterization of Sulfur-Doped Nanosized TiO(2) and Photocatalytic Degradation of Methylene Blue Under Visible Light”, Catal. Lett., 2010, 139, 77-84.
[24]Kanaparthi Ramesh, Chang Jie, Yi-Fan Han, Armando Borgna, “Synthesis, Characterization and Reactivity of H3PO4 Modified H-ZSM-5 Catalysts for Ethanol Dehydration”, Ind. Eng. Chem. Res., 2010, 49, 4080-4090
[25]Kanaparthi Ramesh, Zheng Jia’E, Goh Yi Ling Eileen, Yi-Fan Han, Armando Borgna, “Synthesis, Characterization and Catalytic Activity of Uniformly Crystalline LaPO4 NanoFiber Catalysts for Ethanol Dehydration”, J. Phys. Chem. C., 2009, 113, 16530-16537.
[26]C. Burato, S. Campestrini, Yi-Fan Han, P. Canton, P. Centomo, P. Canu, B. Corain, “Chemoselective and Re-usable Heterogeneous Catalysts for the Direct Synthesis of Hydrogen Peroxide in the Liquid Phase under Non-explosive Conditions and in the Absence of Chemoselectivity Enhancers”, Appl. Catal. A: Gen., 2009, 358, 224-231.
[27]Kanaparthi Ramesh, Lau Mei Hui, Yi-Fan Han, Armando Borgna, “Structure and reactivity of phosphorous modified H-ZSM-5 catalysts for ethanol dehydration” Catal. Comm., 2009, 10, 567.

 



   
     
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