徐晶


徐晶，教授，博士生导师，教育部新世纪优秀人才，上海市“浦江人才”。通过动态现场原位（Operando）谱学技术对工业催化剂进行多尺度时空表征，构筑真实反应条件下能源和环境领域催化剂全生命周期的动态构-效关系，建立催化剂活性中心结构的定向诱导策略。近年来负责国家重点研发计划课题、国家自然科学基金、上海市科委和中石油等项目16项。发表SCI论文60余篇，授权专利7项。

于1997年和2003年获得天津大学学士、硕士学位。2008年获得新加坡国立大学博士学位。博士毕业后，继续在新加坡国立大学作博士后研究工作。2009年12月开始在华东理工大学化学工程联合国家重点实验室工作。通过发展动态现场原位（Operando）谱学技术对工业催化剂进行多尺度时空表征，构筑能源、环境领域工业催化剂在真实反应条件下全生命周期动态构-效关系，建立催化剂活性中心结构的定向诱导策略，提高工业催化剂研发效率。发表SCI论文60余篇包括J. Am. Chem. Soc. 3篇，J. Catal. 10篇, 化工三大期刊10篇，ACS Catal. 3篇，J. Phys. Chem. C/Lett. 5篇。作为课题负责人，承担国家重点研发计划课题（1项），国家重点研发计划子课题（1项）、国家自然科学基金（3项）、高等学校博士学科点专项科研基金、上海市浦江人才计划、上海市教委科研创新重点项目、教育部新世纪优秀人才项目、上海市自然科学基金等科研项目16项。2011年入选上海市“浦江人才计划”，2012年入选“教育部新世纪人才”，2013 年华东理工大学“青年风采女教师”，2014年华东理工大学“三八红旗手”，2014年华东理工大学首届校长英才奖。


学科专长

  1. 化学工程，动态现场原位，工业催化


研究方向

1、工业催化剂构-效关系的构建

CO/CO2加氢直接制备高附加值化学品；

高级氧化法处理水中有毒有害污染物

2、多相催化过程结合微观动力学的多尺度模拟

3、动态现场原位表征技术的发展

动态现场原位高压拉曼技术；动态现场原位X射线技术；动态现场原位紫

外技术；原位散射漫反射红外技术


在研和已结题主要项目

  1. 合成气/热解气低温甲烷化催化剂研制与规模化制备（国家重点研发计划课题）

  2. 碳酸乙烯酯加氢反应器设计与物料热力学特性测定（国家重点研发计划子课题）

  3. 稀土对重整催化剂性能的影响（中石油石油化工研究院项目）

  4. 利用动态现场原位技术研究费-托合成制烯烃铁基催化剂活性相演变机（国家自然科学基金面上项目）

  5. 光解水制氢纳米光催化材料的表界面基础研究（国家自然科学基金重点项目）

  6. 大型抗结焦乙烯裂解炉关键技术研发（上海卓然工程技术有限公司）

  7. 工业催化剂设计及反应机理研究（教育部新世纪人才支持计划）

  8. CO直接加氢合成乙醇Cu-Co双金属催化体系关键基础问题研究（国家自然科学基金面上项目）

  9. CO加氢制乙酸Rh基催化剂助剂设计的密度泛函理论研究（国家自然科学基金青年基金）

  10. 分子模拟与实验技术协同设计合成洁净能源催化剂（教育部留学回国人员科研启动基金）

  11. CO加氢直接生成乙酸反应机理的密度泛函理论和实验研究 （上海市浦江人才计划）

  12. 非均相Fenton体系新型高效催化剂的宏量制备和连续工艺设计与优化（上海市产学研项目）

  13. 合成气直接制C2化学品关键基础问题研究（上海市教委科研创新重点项目）

  14. CO加氢直接生成C2含氧有机物Rh基纳米反应器的设计和机理研究（教育部基本科研业务费）

  15. CO直接催化加氢合成醋酸、乙醛和乙醇（上海市自然科学基金）

  16. 密度泛函理论结合原位光谱技术对合成气直接制乙酸Rh基催化剂机理研究（高等学校博士学科点专项科研基金（新教师））


近期代表性论文

  1. Yuming Sun, Hao Wang, Ping Li, He Geng, Jing Xu, Yi-fan Han, “Effects of Facet Orientation of γ-Al2O3 Support on Pd Nanoparticles Catalyzed H2O2 Direct Synthesis”, Eur. J. Inorg. Chem., accepted.

  2. Yong-Xiao Tuo, Liu-Jie Shi, Hong-Ye Cheng, Yi-An Zhu, Ming-Lei Yang, Jing Xu, Yi-Fan Han, Ping Li*, Wei-Kang, Yuan, “Insight into the support effect on the particle size effect of Pt/C catalysts in dehydrogenation”, J. Catal, 2018, 360, 175-186

  3. Doudou Ding, Xingyan Xu, Pengfei Tian, Xianglin Liu, Jing Xu*, Yi-Fan Han*, “Promotional effects of Sb on Pd-based catalysts for the direct synthesis of hydrogen peroxide at ambient pressure”, Chinese J. Catal., DOI:10.1016/S1872-2067(18)63031-1

  4. Yulong Zhang, Donglong Fu, Xianglin Liu, Zhengpai Zhang, Chao Zhang, Bianfang Shi, Jing Xu*, and Yi-Fan Han*, “Operando Spectroscopic Study of Dynamic Structure of Iron Oxide Catalysts during CO2 Hydrogenation”, ChemCatChem, 2017, 10,1272

  5. Yulong Zhang, Guangyin Shao, Zhengpai Zhang, Xianglin Liu, Chao Zhang, Jing Xu*, Yi-Fan Han, “Catalytic CO2 Hydrogenation to Lower Olefins: Effect of Activation Atmospheres on Structure-Performance Relationship over K-promoted Fe Catalysts ”CIESC J,2018,1-11

  6. Bianfang Shi, Binbin Zha, Jun Zhang, Zhengpai Zhang, Jing Xu*, Yifan Han, “Iron supported on PANI-derived N-containing carbon materials for direct conversion of syngas to light olefins: Effect of support carbonization temperature” CIESC J,2018,1-12

  7. Yiyi Sheng, Yang Sun, Jing Xu*, Jie Zhang, Yi-fan Han*. "Fenton-like degradation of rhodamine B over highly durable Cu-embedded alumina: Kinetics and mechanism." AIChE Journal, 2018,64,538-549

  8. Zhengpai Zhang, Weiwei Dai, Xinchao Xu, Jun Zhang, Bianfang Shi, Jing Xu*, Weifeng Tu, Yi-fan Han*. “MnOx Promotional Effects on Olefins Synthesis Directly from Syngas over Bimetallic Fe-MnOx/SiO2 Catalysts.” AIChE Journal., 2017,63,4451-4464

  9. Huan-huan Shang, Xiao-man Zhang, Jing Xu*, Yi-Fan Han, “The effects of preparation approaches on the origin of active sites of CuO/CeO2 catalysts for CO oxidation”, Front. Chem. Sci. Eng. 2017, 11(4): 603–612.

  10. Guoheng Yin, Xieyi Huang, Tianyuan Chen, Wei Zhao, Qingyuan Bi, Jing Xu, Yifan Han, and Fuqiang Huang, “Hydrogenated Blue Titania for Efficient Solar to Chemical Conversions: Preparation, Characterization, and Reaction Mechanism of CO2 Reduction”, ACS Catal. 2018, 8(2), 1009-1017.

  11. Pengfei Tian, Like Ouyang, Xingyan Xu, Can Ao, XinchaoXu, Rui Si, Xiangjian Shen, Ming Lin, Jing Xu and Yi-Fan Han*, “The origin of the palladium particle size effects in the direct synthesis of H2O2: Is smaller better?”, J. Catal, 2017, 349, 30-40

    12. Guangyin Shao ,Yulong Zhang, Zhengpai Zhang, Jun Zhang, Junjie Su, Da Liu,  Chongheng He, Jing Xu* and Yi-Fan Han, “Study of CO2 hydrogenation over Fe catalysts supported on ZSM-5 zeolite with different ratios of Si/Al”, CIESC J., 2016, 68, 670-678.

  1. Yuming Sun, Hao Wang, Ping Li*, Xuezhi Duan, Jing Xu and Yi-Fan Han, “Synthesis and identification of hierarchical γ-AlOOH self-assembled by nanosheets with adjustable exposed facets”, CrystEngComm, 2016, 18, 4546-4554.

  2. Can Ao, Pengfei Tian, Like Ouyang, Guojin Da, Xingyan Xu, Jing Xu and Yi-Fan Han*, “Dispersing Pd nanoparticles on N-doped TiO2: A highly selective catalyst for H2O2 synthesis”, Catal. Sci. & Technol., 2016, 6, 5060-5068.

  3. Jing Xu*, Xin-Chao Xu, Xue-Jing Yang, and Yi-Fan Han, “Silver/hydroxyapatite foam as a highly selective catalyst for acetaldehyde production via ethanol oxidation”, Catal. Today, 2016, 276, 19-27.

  4. Xiao-Man Zhang, Ya-Qing Deng, Pengfei Tian, Huan-Huan Shang, Jing Xu and Yi-Fan Han*, “Dynamic active sites over binary oxide catalysts: In situ/operando spectroscopic study of low-temperature CO oxidation over MnOx-CeO2 catalysts”, Appl. Catal. B: Environ., 2016, 305, 178-189.

  5. Yulong Zhang, Donglong Fu, Xingyan Xu, Yiyi Sheng, Jing Xu and Yi-Fan Han*, “Application of operando spectroscopy on catalytic reactions”, Curr. Opin. Chem. Eng., 2016, 12, 1-7.

  6. Xue-Jing Yang, Peng-Fei Tian, Hua-Lin Wang, Jing Xu and Yi-Fan Han*, “Catalytic decomposition of H2O2 over a Au/carbon catalyst: A dual intermediate model for the generation of hydroxyl radicals”, J. Catal, 2016, 336, 126-132.

  7. Junjie Su, Zhengpai Zhang, Donglong Fu, Da Liu, Xin-Chao Xu, Bianfang Shi, Xu Wang, Rui Si, Zheng Jiang, Jing Xu and Yi-Fan Han*, “Higher alcohols synthesis from syngas over CoCu/SiO2 catalysts: Dynamic structure and the role of Cu”, J. Catal, 2016, 336, 94-106.

  8. Xue-Jing Yang, Xi-Meng Xu, Xin-Chao Xu, Jing Xu, Hua-Lin Wang, Raphael Semiat and Yi-Fan Han*, “Modeling and kinetics study of Bisphenol A (BPA) degradation over an FeOCl/SiO2 Fenton-like catalyst”, Catal. Today, 2016, 276, 85-96.

  9. Xin Yu, Ting Wu, Xue-Jing Yang, Jing Xu, Jordan Auzam, Raphael Semiat and Yi-Fan Han*, “Degradation of trichloroethylene by hydrodechlorination using formic acid as hydrogen source over supported Pd catalysts”, J. Hazard Mater., 2016, 305, 178-189.

  10. Jun Zhang, Zhengpai Zhang, Junjie Su, Donglong Fu, Weiwei Dai, Da Liu, Jing Xu and Yi-Fan Han*, “Effect of support basicity on iron-based catalysts for Fischer-Tropsch synthesis”, CIESC J., 2016, 67, 549-556.

  11. Weiwei Dai, Da Liu, Donglong Fu, Zhengpai Zhang, Jun Zhang, Jing Xu and Yi-Fan Han*, “Kinetics study of Fischer-Tropsch reaction to lower olefins over MnOx-promoted Fe/SiO2 catalysts”, CIESC J., 2015, 66, 3444-3455.

  12. Wei Mao, Junjie Su, Zhengpai Zhang, Xin-Chao Xu, Donglong Fu, Weiwei Dai, Jing Xu*, Xinggui Zhou, Yi-Fan Han*, “A mechanistic basis for the effects of Mn loading on C2+ oxygenates synthesis directly from syngas over Rh–MnOx/SiO2 catalysts”, Chem. Eng. Sci., 2015, 135, 301-311.

  13. Wei Mao, Junjie Su, Zhengpai Zhang, Xin-Chao Xu, Weiwei Dai, Donglong Fu, Jing Xu*, Xinggui Zhou and Yi-Fan Han, “Kinetics study of C2+ oxygenates synthesis from syngas over Rh–MnOx/SiO2 catalysts”, Chem. Eng. Sci., 2015, 135, 312-322.

  14. Xinchao Xu, Junjie Su, Pengfei Tian, Donglong Fu.,Weiwei Dai,Wei Mao,Weikang Yuan, Jing Xu and Yi-Fan Han*, “First-principles study of C2 oxygenates synthesis directly from syngas over CoCu bimetallic catalysts”, J. Phys. Chem. C.,2015, 119, 216-227.

  15. Donglong Fu, Weiwei Dai, Xin-Chao Xu, Wei Mao, Junjie Su, Zhengpai Zhang, Bianfang Shi, Julian Smith, Ping Li, Jing Xu and Yi-Fan Han*, "Probing The Structure Evolution of Iron-Based Fischer–Tropsch to Produce Olefins by Operando Raman Spectroscopy", ChemCatChem, 2015, 7, 752-756.

  16. Like Ouyang, Peng-Fei Tian, Guo-jin Da, Xin-Chao Xu, Can Ao, Tian-yuan Chen, Rui Si, Jing Xu and Yi-Fan Han*, “The origin of active sites for direct synthesis of H2O2 on Pd/TiO2 catalysts: Interfaces of Pd and PdO domains”, J. Catal., 2015, 321, 70-80.

  17. Xue-jing Yang, Peng-Fei Tian, Xiao-man Zhang, Xin Yu, Ting Wu, Jing Xu and Yi-Fan Han*, “The generation of hydroxyl radicals by hydrogen peroxide decomposition on FeOCl/SBA-15 catalysts for phenol degradation”, AIChE J., 2015, 61, 166-175.

  18. Like Ouyang, Longfei Tan, Jing Xu, Peng-fei Tian, Guo-jin Da, Xue-Jing Yang, Dong Chan, Fangqiong Tang and Yi-Fan Han*, “Functionalized silica nanorattles hosting Au nanocatalyst for direct synthesis of H2O2”, Catal. Today, 2015, 248, 28-34.

  19. Jing Xu , Ya-Qing Deng , Xiao-Man Zhang , Yan Luo , Wei Mao , Xue-Jing Yang , Like Ouyang , Pengfei Tian , and Yi-Fan Han*, “Preparation, Characterization, and Kinetic Study of a Core–Shell Mn3O4@SiO2 Nanostructure Catalyst for CO Oxidation”, ACS Catal., 2014, 4, 4106–4115.

  20. Junjie Su, Wei Mao, Xin-Chao Xu, Zhen Yang, Honglin Li, Jing Xu and Yi-Fan Han*,“Kinetic study of higher alcohol synthesis directly from syngas over CoCu/SiO2 catalysts”, AIChE J., 2014, 60,1797-1809.

  21. Junjie Su, Wei Mao, Zhen Yang, Jing Xu and Yi-fan Han*, “Kinetics of CoCu/SiO2 for synthesis of lower carbon mixed alcohols directly from syngas”, CISEC J., 2014, 65,143-151.

  22. Like Ouyang, Guo-jin Da, Peng-Fei Tian, Tian-yuan Chen, Guo-Da Liang, Jing Xu and Yi-Fan Han*, “Insight into active sites of Pd-Au/TiO2 catalysts in hydrogen peroxide synthesis directly from H2 and O2”, J. Catal., 2014, 311, 129-136.

  23. Like Ouyang, Guojin Da, Pengfei Tian, Tianyuan Chen, Jing Xu and Yi-Fan Han*,“Kinetic study of synthesis of hydrogen peroxide directly from H2 and O2 over Pd/HAp catalyst”, CISEC J., 2014, 65,152-159.

  24. Xue-Jing Yang, Xi-Meng Xu, Jing Xu and Yi-Fan Han*, “Iron oxychloride (FeOCl): An efficient Fenton-like catalyst for producing hydroxyl radicals in degradation of organic contaminants”, J. Am. Chem. Soc., 2013, 43, 16058-16061.

  25. Guo-Jin Da, Like Ouyang, Jing Xu, Yi-Fan Han*, “Pyridine modified Pd/SiO2 catalyst for direct synthesis of H2O2”, CISEC J., 2013, 64, 561-567.

  26. Jing Xu, Ya-Qing Deng, Yan Luo, Wei Mao, Xue-Jing Yang and Yi-Fan Han*, “Operando raman spectroscopy and kinetic study of low-temperature CO oxidation on an α-Mn2O3 nanocatalyst”, J. Catal., 2013, 300, 225-234.

  27. Pengfei Tian, Like Ouyang, Xinchao Xu, Jing Xu and Yi-Fan Han*, “Density functional theory study of direct synthesis of H2O2 from H2 and O2 on Pd(111), Pd(100), and Pd(110) surfaces”, Chin. J. Catal., 2013, 34, 1002-1012.

  28. Like Ouyang, Guo-Jin Da, Jun Ni, Jing Xu and Yi-Fan Han*, “Heterogeneous catalysis by gold-based bimetallic catalysts”, Recent Patents on Catalysis, 2013, 2, 2-46.

  29. Qingsen Meng, Yongli Shen, Jing Xu, Xinbin Ma and Jinlong Gong*, “Mechanistic understanding of hydrogenation of acetaldehyde on Au(111): A DFT investigation”, Surf. Sci., 2012, 606, 1608-1617.

  30. Qingsen Meng, Yongli Shen, Jing Xu and Jinlong Gong*, “Mechanistic insights into selective oxidation of ethanol on Au(111): A DFT study”, Chin. J. Catal., 2012, 33, 407-415.

  31. Teng Zhou, Ziyun Wang, Yinmei Ye, Lifang Chen, Jing Xu and Zhiwen Qi*, “Deep separation of benzene from cyclohexane by liquid extraction using ionic liquids as the solvent”, Ind. Eng. Chem. Res., 2012, 51, 5559-5564.

  32. Xuejing Yang, Peng-Fei Tian, Chengxi Zhang, Ya-qing Deng, Jing Xu, Jinglong Gong and Yi-Fan Han*, “Au/carbon as Fenton-like catalysts for the oxidative degradation of bisphenol A”, Appl. Catal. B: Environ., 2013, 134-135, 145-152.

  33. Yan Luo, Ya-Qing Deng, Wei Mao, Xue-Jing Yang, Kake Zhu, Jing Xu, and Yi-Fan Han*, “Probing the surface structure of α-Mn2O3 nanocrystals during CO oxidation by Operando Raman Spectroscopy”, J. Phy. Chem. C., 2012, 116, 20975-20981.

  34. Jing Xu, Like Ouyang, Wei Mao, Xue-Jing Yang, Xin-Chao Xu, Jun-Jie Su, Hui Li and Yi-Fan Han*, “Operando and kinetic study of low-temperature lean-burn methane combustion over a Pd/-Al2O3 catalyst”, ACS Catal., 2012, 2, 261-269.

  35. Jing Xu, Xin-Chao Xu, Like Ouyang, Xue-Jing Yang, Wei Mao, Junjie Su and Yi-Fan Han*,“Mechanistic study of preferential CO oxidation on a Pt/NaY zeolite catalyst”, J. Catal., 2012, 287, 114-123.

  36. Jing Xu, Like Ouyang, Yan Luo, Xi-Meng Xu, Zhen Yang, Chengxi Zhang, Jinlong Gong* and Yi-Fan Han*,“Mechanistic insights into Methanol-to-Olefin reaction on an α-Mn2O3 nanocrystal catalyst”, AIChE J., 2012, 58, 3474-3481.

  37. Jing Xu, Like Ouyang, Guo-Jin Da, Qian-Qian Song, Xue-Jing Yang and Yi-Fan Han*, “Pt promotional effects on Pd-Pt alloy catalysts for hydrogen peroxide synthesis directly from hydrogen and oxygen”, J. Catal., 2012, 285, 74-82.

  38. Kong Fei Tan, Jing Xu, Jie Chang, Armando Borgna and Mark Saeys*, “Carbon deposition on Co catalysts during Fischer–Tropsch synthesis: A computational and experimental study”, J. Catal., 2010, 274, 121-129.

  39. Jing Xu, Tim White, Ping Li, Chongheng He and Yi-Fan Han*, “Hydroxyapatite foam as a catalyst for formaldehyde combustion at room temperature”, J. Am. Chem. Soc., 2010, 132, 13172-13173.

  40. Jing Xu, Tim White, Ping Li, Chongheng He, Jianguo Yu, Weikang Yuan and Yi-Fan Han*, “Biphasic Pd-Au alloy catalyst for low-temperature CO oxidation”, J. Am. Chem. Soc., 2010,132,10398-10406.

  41. Jing Xu, Ping Li, Xingfu Song, Chongheng He, Jianguo Yu and Yi-Fan Han*，“Operando Raman spectroscopy for determining the active phase in one- dimensional Mn1−xCexO2±y nanorod catalysts during methane combustion”, J. Phys. Chem. Lett., 2010, 1, 1648-1654.

  42. Jing Xu, Ping Li, Xingfu Song, Zhiwen Qi, Jianguo Yu, Weikang Yuan and Yi-Fan Han*, “Kinetic study of H2 oxidation in the preferential oxidation of CO on a nanosized Au/CeO2 catalyst”,Ind. Eng. Chem. Res., 2010, 49, 4149-4155.

  43. Jing Xu, Jinhua Yang, Jim Yang Lee and Mark Saeys*, “Design of an oxygen reduction catalyst for direct methanol fuel cells”, Ind. Eng. Chem. Res., 2010, 49, 10251-10253.

  44. Jing Xu, Luwei Chen, Kong Fei Tan, Armando Borgna* and Mark Saeys*, “Effect of boron on the stability of Ni catalysts”,J. Catal., 2009, 261, 158-165.

  45. Jing Xu and Mark Saeys*, “First principles study of the effect of carbon and boron on the activity of a Ni catalyst”,J. Phys. Chem. C, 2009, 113, 4099-4106.

  46. Jing Xu and Mark Saeys*, “First principles study of the stability and the formation kinetics of subsurface and bulk carbon on a Ni catalyst”,J. Phys. Chem. C, 2008, 112, 9679-9685.

  47. Jing Xu and Mark Saeys*, “First principles study of the coking resistance and the activity of a boron promoted Ni catalyst”,Chem. Eng. Sci., 2007, 62, 5039-5041.

  48. Jing Xu and Mark Saeys*, “Improving the coking resistance of Ni-based catalysts by promotion with subsurface boron”,J. Catal., 2006, 242, 217-226.


近期代表专利

  1. 韩一帆、徐晶、杨雪晶、徐西蒙、罗妍，“用于非均相Fenton体系的负载型固体催化剂” 申请号：201110407439.2

  2. 韩一帆、罗妍、徐晶、朱卡克、邓雅晴、李平，“一种MOx@SiO2壳-核结构催化剂的制备方法” 申请号：201210153898.7 授权2016-12-7

  3. 韩一帆、徐晶、茅威、苏俊杰、付东龙、欧阳李科、笪国进，“高温高压动态现场原位光谱测量用的气固相原位反应池” 申请号：201410003940.6

  4. 韩一帆、徐晶、张俊、张征湃、尚欢欢，“一种防污染型高温高压动态现场原位光谱测试用反应器” 申请号：201610645818.8

  5. 韩一帆、徐晶、张俊、张征湃、辛玮玥，“一种用于动态现场原位光谱测试的防冷凝型反应器” 申请号：201610424781.6

  6. 韩一帆、徐晶、张俊、辛玮玥、张征湃，“一种自清洁式高温高压动态现场原位光谱测试用反应器” 申请号：201610645836.6

  7. 李平、王寅、李富国、徐晶、韩一帆、周兴贵，“一种二甲醚水蒸气重整制氢催化剂的制备及应用”，ZL201010169764.5，授权2012-07-25

  8. 李平、王寅、王西龙、徐晶、韩一帆、周兴贵，“一种堇青石蜂窝的涂层方法”，ZL200 10219299.1，授权2012-12-19

  9. 李平、张世渊、吴一宁、徐晶、韩一帆、周兴贵，“一种导电材料及其制备方法和用途”，ZL 201010183853.5，授权2013-10-02

  10. 韩一帆、徐晶、李洪临、戴薇薇、苏俊杰、吴婷，“一种用于合成气制取低碳烯烃的催化剂的制备方法及应用” ZL201310285493.3，授权2015-02-18

  11. 韩一帆、徐晶、徐西蒙、杨雪晶、杨震，“一种处理工业废水的非均相Fenton反应连续装置及处理工艺” ZL 2011 1 0355576.6，授权2015-05-27

  12. 石变芳、刘达、徐晶、韩一帆、李平、戴薇薇、苏俊杰，“一种铁基催化剂及其制备方法和应用”，申请号：201510253235.6

  13. 李平、孙钰铭、徐晶、韩一帆、任乐乐、叶黎城、周兴贵，“一种整体型一氧化氮低温氧化催化剂及其制备方法”， 申请号：201410150902.3，授权2016-05-18

  14. 韩一帆 徐晶 李平 张玉龙 邵光印，一种用于二氧化碳加氢制取低碳烯烃催化剂的制备方法及应用，申请号：201710813409.9
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